GENERAL
Electric conductivity is defined as the
ability of a solution to conduct an electric
current and it is the reciprocal of electrical
resistivity. The unit of measurement commonly
used is the micro mhos or mili mhos.
In aqueous solutions conductivity is directly
proportional to the concentration of dissolved
solids. Therefore higher the concentrations
of solids, greater the conductivity. The
relation between conductivity and Total
dissolved solids (TDS) is expressed, depending
on the application and with a good approximation
by :-
TDS = .63 conductivity approx.
[where PPM i.e. mg/l is the measuring unit
for dissolved solids]
The conductivity of a solution is determined
by molecular motion. Temperature affects
molecular motion and it is therefore important
to compensate for temperature when accurate
and precise measurement are necessary. For
comparative measurements, the standard temperature
is normally 200 C or 250 C [680 F or 770
F].
LABMED digital conductivity / TDS meter
is accurate, rugged and reliable instruments.
Two models are available.
These are : -
(a) Hand Held Model LM 301
– 9 V DC operated only (TDS Mode).
(b) Table Model LM 401
– Mains / 9 V DC operated (TDS / Conductivity
mode).
It is possible to differentiate conductivity
meter according to the measurement method
they use i.e. amperometric or potentiometric.
The potentiometric system applies a known
potential difference (V) to the electrode
and measure the current (I) that passes
through them. According to ohms law I =
V / R.
Where R is resistance, V is the known voltage
and I is the current going from the electrode
to the other. It follows that the higher
the current obtained, the greater the conductivity.
The resistance however depends on the distance
between the two electrodes and their surfaces,
which can vary due to deposits of salts
or other materials (electrolysis). The using
potentiometric method is based on the principle
of induction and eliminates common problem
of effect of polarization. An alternating
voltage is applied to the outer rings and
induce a current loop in the solutions.
It is possible (approximation only) to obtain
the value of hardness of water in French
degree [0F]. The main cause of hard water
is the presence of dissolved calcium and
magnesium ions. The most common unit of
hardness is French degree [0F]. Dividing
the PPM measurement of TDS by 10 gives only
approximate value of hardness with an error
of 4 – 5 0F. [10 F = 10 PPM of CaCO3].
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